From electrically conductive MOFs to sustainable batteries

By Prof. Mircea Dincă, Department of Chemistry, Massachusetts Institute of Technology (Webpage).

Date and Venue: October 1st, 2024 at 12.00h – Aula Magna Enric Casassas (Faculties of Physics and Chemistry UB)

(Chaired by Prof. Guillem Aromí, IN²UB and Faculty of Chemistry)

Full information: IN2UB webpage

ABSTRACT

The emergence of electrically conductive metal-organic frameworks (c-MOFs) has been one of the most paradoxical developments in the field in the last few years. Indeed, how can one transport charges through a material that is mostly “empty” space? In this sense, MOFs made from layers of organic ligands connected by (typically) square-planar metal ions have shown particularly good electrical conductivity. However, a precise mechanism for charge transport is still the subject of debate, with various experimental and computational reports describing these materials as metals, semiconductors, or semimetals. This lecture will describe the latest efforts from our group to understand the intrinsic properties of 2D c-MOFs, especially as related to single-crystal electrical measurement studies, and will discuss in particular the unexpectedly large influence of out-of-plane transport. Time allowing, I will discuss unexpected results stemming from the behavior of these materials as 1D metals, and applications in energy storage and conversion.